Blake Shelton and Gwen Stefani to Perform Their Duet at the Billboard Music Awards

Blake Shelton and Gwen Stefani
Kevin Winter/Getty Images for iHeartMedia

It's music to our ears – Blake Shelton and Gwen Stefani are set to perform their new duet "Go Ahead and Break My Heart" at the Billboard Music Awards later this month.

The duo made their debut performance of the song on The Voice Monday night, showing off their undeniable chemistry on stage.

"We both had trust issues. We were getting over it, but we wrote this song about it, and it's perfect," Shelton told PEOPLE exclusively before the performance.

This year's Billboard Music Awards will be hosted by Ludacris and Ciara, and previously announced performers include Justin Bieber, DNCE, Demi Lovato, Celine Dion (who is also receiving the Icon Award), Britney Spears and Ariana Grande.

Another highly anticipated performance includes Madonna's tribute to her friend and late legend Prince.

The 2016 Billboard Music Awards will be broadcast live from the T-Mobile Arena in Las Vegas on May 22 at 8 p.m. on ABC.